Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly By
2011 | 834 Pages | ISBN: 0470825138 | PDF | 110 MB
The field of CMA (complex macromolecular architecture) stands at the cutting edge of materials science, and has been a locus of intense research activity in recent years. This book gives an extensive description of the synthesis, characterization, and self-assembly of recently-developed advanced architectural materials with a number of potential applications. The architectural polymers, including bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil block copolymers, are introduced chapter by chapter in the book. In particular, the book also emphasizes the topic of synthetic breakthroughs by living/controlled polymerization since 2000. Furthermore, renowned authors contribute on special topics such as helical polyisocyanates, metallopolymers, stereospecific polymers, hydrogen-bonded supramolecular polymers, conjugated polymers, and polyrotaxanes, which have attracted considerable interest as novel polymer materials with potential future applications. In addition, recent advances in reactive blending achieved with well-defined end-functionalized polymers are discussed from an industrial point of view. Topics on polymer-based nanotechnologies, including self-assembled architectures and suprastructures, nano-structured materials and devices, nanofabrication, surface nanostructures, and their AFM imaging analysis of hetero-phased polymers are also included. Provides comprehensive coverage of recently developed advanced architectural materialsContent: Chapter 1 Cyclic and Multicyclic Topological Polymers (pages 1-19): Takuya Yamamoto and Yasuyuki TezukaChapter 2 Ultrarapid Approaches to Mild Macromolecular Conjugation (pages 21-52): Andrew J. Inglis and Christopher Barner?KowollikChapter 3 Synthesis and Self?Assembly of Hydrogen?Bonded Supramolecular Polymers (pages 53-95): Wolfgang H. Binder, Claudia Enders, Florian Herbst and Katharina HackethalChapter 4 Recent Synthetic Developments in Miktoarm Star Polymers with More than Three Different Arms (pages 97-132): Akira Hirao, Mayumi Hayashi, Tomoya Higashihara and Nikos HadjichristidisChapter 5 Precise Synthesis of Dendrimer?Like Star?Branched Polymers, a New Class of Well?Defined Hyperbranched Polymers (pages 133-167): Hee?Soo Yoo and Akira HiraoChapter 6 Arborescent Polymers with a Mesoscopic Scale (pages 169-194): Toufic Nabil Aridi and Mario GauthierChapter 7 Hyperbranched Glyco?Conjugated Polymers (pages 195-227): Toshifumi Satoh and Toyoji KakuchiChapter 8 Highly Branched Functional Polymer Architectures by Click?Chemistry Strategies (pages 229-265): Mieke Lammens and Filip Du PrezChapter 9 Living Alkene Polymerization for Polyolefin Architectures (pages 267-316): Amelia M. Anderson?Wile, Joseph B. Edson and Geoffrey W. CoatesChapter 10 Precision Polyolefins (pages 317-347): Erik B. Berda and Kenneth B. WagenerChapter 11 Polyhomologation: The Living Polymerization of Ylides (pages 349-376): Jun Luo and Kenneth J. SheaChapter 12 Phenylenevinylene Homopolymers and Block Copolymers via Ring?Opening Metathesis Polymerization (pages 377-393): Chin?Yang Yu and Michael L. TurnerChapter 13 Block Copolymers Containing Rod Segments (pages 395-429): Tomoya Higashihara and Mitsuru UedaChapter 14 Synthesis of Well?Defined Poly(meth)acrylamides with Varied Stereoregularity by Living Anionic Polymerization (pages 431-460): Takashi IshizoneChapter 15 Complex Macromolecular Chimeras (pages 461-489): Hermis Iatrou, Marinos Pitsikalis, Georgios Sakellariou and Nikos HadjichristidisChapter 16 Self?Assembly and Applications of Polyferrocenylsilane Block Copolymers (pages 491-526): George R. Whittell, Jessica Gwyther, David A. Rider and Ian MannersChapter 17 Functional Polymeric Nanostructures Prepared by Self?Assembly and Beyond (pages 527-567): Rachel K. O'ReillyChapter 18 Morphologies of Block and Star?Branched Polymers with Three Components (pages 569-591): Hirokazu HasegawaChapter 19 Morphologies and Photophysical Properties of Conjugated Rod-Coil Block Copolymers (pages 593-622): Chi?Ching Kuo, Cheng?Liang Liu and Wen?Chang ChenChapter 20 Bulk Self?Assembly of Linear Hybrid Polypeptide?Based Diblock and Triblock Copolymers (pages 623-645): Sebastien LecommandouxChapter 21 AFM Study of Comb (Co)Polymers with Complex Chain Architecture (pages 647-683): Michel Schappacher and Alain DeffieuxChapter 22 Tunable Thermoresponsive Polymers by Molecular Design (pages 685-715): Richard HoogenboomChapter 23 Fluorine?Containing Block Copolymers: Synthesis and Application as a Template for Nanocellular and Porous Structures Using Supercritical Carbon Dioxide (pages 717-737): Hideaki Yokoyama and Kenji SugiyamaChapter 24 Architectural Polymers, Nanostructures, and Hierarchical Structures from Block Copolymers (pages 739-761): Ian Wyman and Guojun LiuChapter 25 Block Copolymer Nanostructured Thin Films for Advanced Patterning (pages 763-790): Michelle A. Chavis, Evan L. Schwartz and Christopher K. OberChapter 26 Ring Polymers: Effective Isolation and Unique Properties (pages 791-821): Haskell W. Beckham